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Hi Sebastian,
Good question - certainly the branch-ends can stack up quickly, and adding effects can become a time-consuming exercise!
The simplest solution that I can recommend would be to simply right-click anywhere in the tree, and select 'Add IPCC Tier 1 Factors to All Branches'. Make sure that you have enabled 'Energy Sector Environmental Loadings' in Basic Parameters first, of course.
This operation will add loadings to each branch from the IPCC Tier 1 emissions factors, using LEAP's best guess for the most appropriate emission factor based on the branch name and fuel. It is an extremely good idea to review these additions, to ensure that the emissions factors that are assigned are sensible.
If you have your own emissions factors that you would like to assign instead, this is a good opportunity to perform an Export to Excel, modify the appropriate emissions factors, and then re-import back into LEAP. This is not possible without first adding the necessary branches - perhaps this is why you found that importing from Excel was not successful, the first time?
LEAP does provide a comprehensive API for scripting, should you wish to approach the problem that way:
http://www.energycommunity.org/WebHelpPro/API/API.htm
Let me know if you'd like some additional information, but I think that the route I have suggested is easiest for your purposes.
Best,
Taylor