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Glad to hear it Daniel,
In terms of GWP calculations, LEAP first calculates the physical emissions of each pollutant (ie Tonnes of CO2, CH4, etc.) You can then display GWP values (ie Tonnes of CO2e) by applying the 20, 100 or 500 year GWP values.
You can look in the General: Effects screen to see these GWP values for each gas and you can choose whether you want to use the GWP values from the IPCC 2nd, 3rd or 4th assessment reports. I have not (yet) added in the values from the new 5th assessment report, but will try to do so quite soon. In the meantime, you can edit the values yourself manually.
BTW - it seems that for National Communications countries have agreed to use the GWP values from the 2nd assessment report so as to make their reports comparable. Of course their is a trade off between comparability and scientific accuracy.
I hope this helps,
Charlie