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Hi Oriol,
You can edit fuel properties (or add new fuels) by clicking either the 'Fuel' button in LEAP's toolbar, or selecting General: Fuels from LEAP's main menu. Both options bring up the fuels database, in which you can edit the Net Energy Content of each fuel:
www.energycommunity.org/WebHelpPro/Supporting_Screens/Fuels.htm
Best,
Taylor