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Hi James,
A complete description of Process Efficiency (and related variables Heat Rate and Losses) is available here through LEAP's help system:
http://www.energycommunity.org/WebHelpPro/Transformation/Efficiency_Data.htm
The Process Efficiency variable is a very important part of LEAP, since it is used to calculate required inputs for a given unit of output. This can impact emissions (which may be specified either per unit of energy produced or consumed by the process), the dispatch of other Transformation modules lower in the tree, as well as analysis of total resource or trade requirements.
LEAP does not include any default power plant data from international sources. However, some good current sources of efficiency and cost data can be found in IPCC's AR5/WG3 Annex III, as well as IEA's Energy Technology Perspectives 2012. These data include many legacy plant types, as well as newer generation technologies.
Take care,
Taylor