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Hi Zhou,
The energy content assigned to fuels in LEAP's database can be thought of as default values. You may change the energy content of fuels as you like (all of the fields in the Fuels database are editable), or create new fuels by clicking on the "+" button on the Fuels screen. You could use this to create a fuel called "Crude Coal", if you wish.
The Carbon Stored variable is the fraction of the carbon in the fuel (by weight) that remains permanently stored when the fuel is used for non-energy purposes. This and other fuel properties are listed in the help pages here (you reference this variable using "NonEnergyCarbonStored"):
http://www.energycommunity.org/WebHelpPro/Expressions/Fuel_Properties.htm
However, this variable has not been used in LEAP for some time.
Hope this help,
Taylor