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Hello Tanya,
This is a very general question. I'd recommend that you review some key help files in LEAP's searchable user manual, available here (and offline, from LEAP's help button):
http://www.energycommunity.org/WebHelpPro/LEAP.htm
Please start with the Demand Analysis section (specifically activity analysis), and then you can move on to transformation calculations:
http://www.energycommunity.org/WebHelpPro/Demand/Demand.htm
Once you review some of these materials, I'd be happy (and probably much more useful to you) to answer specific questions about how the software works if anything remains unclear.
Since LEAP is a tool for building models (not a pre-built model), there is no difference in the way that different sectors are treated from a mathematical point of view. Instead, it is up to the user to specify the units of energy consumption for sectors and subsectors (or any level of sectoral resolution that you wish).
Taylor