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Hi Suman,
Please review this help page:
http://www.energycommunity.org/WebHelpPro/Demand/Demand_Properties_Wizard.htm
...specifically focusing on the difference between "Categories" and "Categories with Energy Intensity". The fuel share variable only appears for technologies underneath the category with energy intensity.
Note that you may also use regular (yellow) categories, in which case you would adjust the activity level of each of your technologies or fuels to reflect a fuel switching scenario.
Best,
Taylor