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Hi Irene,
Thanks for your question. You're correct that typically LEAP is used for modeling larger spatial scales (i.e. countries or regions), but lately I believe there are some applications in cities. It can be appropriate on any spatial scale, but is really intended to model a complete energy system. This covers the production and consumption of all fuels used in a system.
As such, I suspect it is more fully-featured than is needed for your analysis. Still, I would still suggest you try the first exercise in our online training materials to get a feel for its capabilities:
http://www.energycommunity.org/default.asp?action=42
LEAP does permit you to find least-cost capacity expansion and dispatch, with some limitations. You may also find it useful to work through exercise 6 of the training materials, mentioned above. Are you interested in the least-cost mix of hydraulic, thermal and chemical electricity production for a specified level of demand? In this case it would be possible to treat each as a separate process ("power plant"), and allow LEAP to construct and dispatch each in an optimal way.
Hope this helps,
Taylor