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Hi David,
In order to impose an hourly constraint on LEAP's electric dispatch, you'll need to divide each year into hourly time slices:
http://www.energycommunity.org/WebHelpPro/Supporting_Screens/Time_Slices.htm
Though this is technically possible, we almost always recommend against doing so. It's very taxing for LEAP's calculations, and is often an unnecessary level of detail for a scenario analysis that extends out twenty years or more. Instead, I'd suggest that you divide your year into time slices which capture the largest variations in gas supply, and aggregating your hourly data into those time slices. LEAP's time slices provide a great deal of flexibility for you to define slices for days, weeks, night vs. day, etc.
Once you've defined proper time slices, you would implement differing availability of gas using the Maximum Availability variable for your natural gas electricity generation process. This variable supports time-sliced values, which you can enter in one of two ways: using the built-in TimeSliceValue() function or by constructing a new "availability"-type yearly shape
http://www.energycommunity.org/WebHelpPro/Expressions/TimeSliceValue.htm
http://www.energycommunity.org/WebHelpPro/Supporting_Screens/Load_Shapes.htm
If you use the latter option, you'll be able to "Import Hourly Shape" from Excel, which will automatically assign your hourly data from one year to the appropriate time slice you've established.
Can I also ask - are you currently using LEAP, or just exploring what can be done with the tool? If you are currently using it, how did you acquire a license?
All the best,
Taylor