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Hi Maria,
Please define all acronyms used in your forum questions. This helps us answer your questions more clearly, and is useful for other users who may later view this thread.
By "DNI" I assume you mean "Direct Normal Irradiance", and "GHI" means "Global Horizontal Irradiance" - two different varieties of incident solar radiation which are useful for calculating the electricity production from solar photovoltaics (PV).
For a Solar PV process within your electricity generation module, you may input different Maximum Availability values in each time slice of the year. However, it will be up to you to calculate the fraction of installed capacity which is available in each of these slices, based on estimates of the average solar radiation in each time slice.
To include time-sliced information in this variable, use LEAP's TimeSliceValue() or YearlyShape() functions, which you may read about here:
http://www.energycommunity.org/WebHelpPro/Expressions/TimeSliceValue.htm
http://www.energycommunity.org/WebHelpPro/Expressions/YearlyShape.htm
Note that that Maximum Availability variable controls the available capacity which may be used to generate electricity - but it does not directly control the electricity generation using that capacity. For this, you will want to use an appropriate Dispatch Rule for your process (perhaps FullCapacity, for example: www.energycommunity.org/WebHelpPro/Transformation/Process_Dispatch_Rules.htm)
Hope this helps,
Taylor