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Hi Bri,
The Annual Emissions Constraint variable is only visible if you are using LEAP to conduct least-cost optimization. The constraint would then cause LEAP to try to identify a solution within the optimized transformation module which keeps total emissions at or below the value you have set.
For further information, please have a quick look at these links:
http://www.energycommunity.org/WebHelpPro/Transformation/Emission_Constraint.htm
http://www.energycommunity.org/WebHelpPro/Optimization/OptimizationIntroduction.htm
Best,
Taylor